Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan

被引:11
|
作者
Mejia, Elizabeth Henao [1 ]
Contreras, Hector [2 ]
Delgado, Ezequiel [2 ]
Quintana, German [1 ]
机构
[1] Univ Pontificia Bolivariana, Fac Chem Engn, Pulp & Paper Res Grp, Circular 1 70-01, Medellin, Antioquia, Colombia
[2] Univ Guadalajara, Dept Madera Celulosa & Papel DMCyP, Km 15-5,Carretera Guadalajara Nogales, Zapopan 45020, Jalisco, Mexico
关键词
SODIUM ALGINATE; CONTROLLED-RELEASE; CROSS-LINKING; DELIVERY; PH; POLYSACCHARIDES; NANOPARTICLES; MICROSPHERES;
D O I
10.1155/2019/3085691
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Differences in morphology, pH, and electric charge of chitosan (CS) based hydrogels prepared by complexation with carboxymethylcellulose (CMC), carboxymethylated starch (CMS), and alginic acid (AA) at different polymers ratios and changing the order of addition were studied. CMC/CS and AA/CS hydrogels were amorphous and porous three-dimensional networks, with smaller pores at higher anionic polymer/CS ratios. Gelation time increased the agglomeration in the case of CMC/CS and CMS/CS gels. CMC/CS gels showed negative zeta potential values around -372mV to -51mV and CMS/CS gels in the range of -526mV and -158mV.
引用
收藏
页数:13
相关论文
共 10 条
  • [1] Polyelectrolyte Complexation versus Ionotropic Gelation for Chitosan-Based Hydrogels with Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid
    Henao, Elizabeth
    Delgado, Ezequiel
    Contreras, Hector
    Quintana, German
    INTERNATIONAL JOURNAL OF CHEMICAL ENGINEERING, 2018, 2018
  • [2] Stretchable hydrogels of chitosan/hyaluronic acid induced by polyelectrolyte complexation around neutral pH
    Balima, Maeva
    Morfin, Isabelle
    Sudre, Guillaume
    Montembault, Alexandra
    CARBOHYDRATE POLYMERS, 2024, 339
  • [3] Preparation and characterization of carboxymethyl cellulose/chitosan/alginic acid hydrogels with adjustable pore structure for adsorption of heavy metal ions
    Zhang, Rongjuan
    Liu, Baojian
    Ma, Jia
    Zhu, Ruiju
    EUROPEAN POLYMER JOURNAL, 2022, 179
  • [4] Effect of Degree of Substitution and Polymer Ratio on the Structure of Chitosan: Carboxymethyl Starch (Bio)Polyelectrolyte Complexes
    Castro, David
    Brovina, Valentina
    Litvinov, Mikhail
    Podshivalov, Aleksandr
    POLYMERS, 2024, 16 (24)
  • [5] Effect of molecular weight and ionic strength on the formation of polyelectrolyte complexes based on poly(methacrylic acid) and chitosan
    de Vasconcelos, CL
    Bezerril, PM
    dos Santos, DES
    Dantas, TNC
    Pereira, MR
    Fonseca, JLC
    BIOMACROMOLECULES, 2006, 7 (04) : 1245 - 1252
  • [6] Effect of Experimental Parameters on the Formation of Chitosan-Poly(acrylic acid) Nanofibrous Scaffolds and Evaluation of their Potential Application as DNA Carrier
    Wang, Jian-Wen
    Chen, Ching-Yi
    Kuo, Yi-Ming
    JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 115 (03) : 1769 - 1780
  • [8] Effect of Starch and Chitosan Addition on Swelling Properties of Neutralized Poly(Acrylic Acid)-Based Superabsorbent Hydrogels Prepared by Using γ-Irradiation Technique
    Barleany, D. R.
    Heriyanto, H.
    Alwan, H.
    Kurniawati, V
    Muyassaroh, A.
    Erizal
    ATOM INDONESIA, 2022, 48 (02) : 99 - 106
  • [9] Effect of experimental parameters on the formation of alginate-chitosan nanoparticles and evaluation of their potential application as DNA carrier
    Douglas, KL
    Tabrizian, M
    JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2005, 16 (01) : 43 - 56
  • [10] EFFECT OF POLYELECTROLYTE COMPLEX-FORMATION ON PH-INDUCED CONFORMATIONAL-CHANGES OF POLYPEPTIDES FOR SYSTEMS OF POLY(L-GLUTAMIC ACID)-POLY(ETHYLENEIMINE) AND POLY(L-LYSINE)-CARBOXYMETHYL CELLULOSE
    SATO, H
    HAYASHI, T
    NAKAJIMA, A
    POLYMER JOURNAL, 1976, 8 (06) : 517 - 523