Heck arylation of conjugated alkenes catalysed by a silica-supported poly-γ-methylselenopropylsiloxane palladium(0) complex, the first polymeric organoselenium palladium complex

被引：0

作者：

Cai, MZ ^{[1
]}

Zhou, J

Zhao, H

Song, CS

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang, Peoples R China

[2] Shangrao Teachers Coll, Dept Chem, Shangrao, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2002年 / 02期

关键词：

Heck anylation; conjugated alkenes; polymeric organoselenium palladium complex;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A silica-supported poly-gamma-methylselenopropylsiloxane palladium(0) complex was prepared from poly-gamma-chloropropylsiloxane by treatment with sodium methyl-seleno late, followed by reaction with palladium chloride and then reduction with hydrazine hydrate. The first polymeric organoselenium palladium complex is a highly active and stereoselective catalyst for the arylation of conjugated alkenes.

引用

页码：76 / 78

页数：3

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