Pervaporation membrane reactor design guidelines for the production of methyl acetate

被引:2
|
作者
Milena Lopez-Zamora, Sandra [1 ]
Fontalvo, Javier [1 ]
Angel Gomez-Garcia, Miguel [1 ]
机构
[1] Univ Nacl Colombia, Fac Ingn & Arquitectura, Lab Intensificac Proc & Sistemas Hibridos, Grp Invest Aplicac Nuevas Tecnol,Dept Ingn Quim, Manizales, Colombia
关键词
Pervaporation membrane reactor; Design methodology; Design charts; Methyl acetate; RESIDUE CURVE MAPS; ACETIC-ACID; CHEMICAL-EQUILIBRIUM; ESTERIFICATION; DEHYDROGENATION; CONVERSION; METHANOL;
D O I
10.1080/19443994.2012.728058
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
m Design guidelines were applied for the production of methyl acetate in a pervaporation membrane reactor. The limits of operation were determined. The shift in equilibrium is evaluated by a simple model involving simultaneously chemical equilibrium and transport across the membrane. This analysis establishes possibilities and limitations of a pervaporation membrane reactor. The performance of a continuous stirred tank reactor with a pervaporation membrane (PV-CSTR) is analyzed. To achieve conversions higher than 90%, conditions must satisfy D-a > 150 and 0.01 < P-e < 100. Increasing temperature has a negative effect on membrane reactor conversion. The effect of sweep is important at high-permeate pressures. Two design charts were created to illustrate dynamics between permeation rates, reaction rates, and selectivity with conversion. The three powerful tools proposed for the analysis of a pervaporation membrane reactor described the system in a systematic way.
引用
收藏
页码:2387 / 2393
页数:7
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