Synthesis and structure of platinum complexes [Ph4P]+[PtCl3(DMSO)]- and [Ph4P]+[PtCl5(DMSO)]-

被引：11

作者：

Sharutin, V. V. ^{[1
]}

Senchurin, V. S. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Gushchin, A. V. ^{[2
]}

机构：

[1] Natl Res S Ural State Univ, Chelyabinsk, Russia

[2] Nizhnii Novgorod State Univ, Nizhnii Novgorod 630600, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 58卷 / 01期

关键词：

CRYSTAL; TRIPHENYLBENZYLPHOSPHONIUM;

D O I：

10.1134/S0036023613010191

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of tetraphenylphosphonium chloride with an equimolar amount of potassium tetrachloroplatinate or hexachloroplatinic acid in dimethyl sulfoxide gave the complexes [Ph4P](+)[PtCl3(DMSO)](-) (I) and [Ph4P](+)[PtCl5(DMSO)](-) (II), respectively. The phosphorus atoms in the cations have tetrahedral environment, the CPC angles and P-C distances 105.63(13)A degrees aEuro"112.13(14)A degrees, 1.795(3)-1.797(3) I) and 105.7(3)A degrees-112.9(3)A degrees, 1.783(7)-1.791(6) II). The platinum coordination polyhedra in the anions [PtCl3(DMSO)](-) and [PtCl5(DMSO)](-) are distorted square (Pt-S, 2.1937(8); Pt-Cl, 2.2894(10)-2.3024(10) ; trans-angles: SPtCl, 177.38(4)A degrees; ClPtCl, 175.40(4)A degrees) and octahedron (Pt-S 2.291(2) ; Pt-Cl, 2.312(2)-2.334(2) , trans-angles: SPtCl, 178.28(9)A degrees; ClPtCl, 178.80(9)A degrees and 178.88(8)A degrees).

引用

页码：33 / 37

页数：5

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