Salts of C60(OH)8 Electrodeposited onto a Glassy Carbon Electrode: Surprising Catalytic Performance in the Hydrogen Evolution Reaction

被引：95
|
作者：
Zhuo, Junqiao [1 ]
Wang, Tanyuan [1 ]
Zhang, Gang [2 ]
Liu, Lu [1 ]
Gan, Liangbing [2 ,3 ]
Li, Meixian [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, Inst Chem, CSA Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
[3] Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 41期
关键词：
electrocatalysis; electrodeposition; fullerenes; hydrogen evolution reaction; FULLERENE DERIVATIVES; RECENT PROGRESS; MOS2; WATER; ACID; NI; NANOPARTICLES; EFFICIENT; FILMS; C-60;
D O I：
10.1002/anie.201305328
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Full(erene) of surprises: The first isomerically pure multi-hydroxylated fullerene, C60(OH)8, shows a reduction peak and a reoxidation peak in aqueous solution. With surprising catalytic performance in the hydrogen evolution reaction (HER), when electrodeposited on a glassy carbon electrode (GCE), salts of C60(OH)8 may prove to be effective molecular catalysts for conducting the HER without transition metals. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10867 / 10870
页数：4
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