Surface Chemistry of Zirconia Nanopowders Doped with Pr2O3: an XPS Study

被引:0
|
作者
Suchorski, Y. [1 ]
Wrobel, R. [2 ]
Becker, S. [2 ]
Opalinska, A. [3 ]
Narkiewicz, U. [4 ]
Podsiadly, M. [4 ]
Weiss, H. [2 ]
机构
[1] Vienna Univ Technol, Inst Mat Chem, A-1210 Vienna, Austria
[2] Otto VonGuericke Univ Magdegurg, Inst Chem, D-39106 Magdeburg, Germany
[3] Polish Acad Sci, Inst High Pressure Phys, PL-01142 Warsaw, Poland
[4] Tech Univ Szczecin, Inst Chem & Environm Engn, PL-70322 Szczecin, Poland
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中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Zirconia nanopowders of tetragonal crystallographic structure doped with Pr(2)O(3) were prepared by the microwave-assisted hydrothermal synthesis and coprecipitation method. The surface compositions were studied by X-ray photoelectron spectroscopy. The nanopowder particles appear to be inhomogeneous in their structure: for the surface region an enrichment with praseodymium is detected by X-ray photoelectron spectroscopy measurements. This allows the assumption of a core-shell-like structure of single nanopowders particles. The X-ray photoelectron spectroscopy studies confirm also Zr(4+) and Pr(3+) as main oxidation states of zirconium and praseodymium in the studied compounds.
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页码:S125 / S134
页数:10
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