Syntheses and crystal structures of the complexes formed by zinc and 4, 4′-bipyridine

被引：0

作者：

Liang, FP

Chen, ZL

Hu, RX

Liang, H ^{[1
]}

Yu, KB

Zhou, ZH

机构：

[1] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China

[2] Chinese Acad Sci, Chengdu Branch, Anal Ctr, Chengdu 610041, Peoples R China

[3] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 17卷 / 05期

关键词：

crystal structure; 4,4 '-bipyridine; picric anion; inclusion phenomenon;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex of the formula [Zn(4, 4'-bpy) (2)(H2O) (2)] (pic) (2) . (H2O) (2) was obtained from the reaction of the zinc picrate and 4, 4'-bipyridine, and characterized by elemental analysis, IR spectrum and X-ray diffraction. It crystallizes in the monoclinic space group Cc with cell parameters a = 1. 4390(2), b = 1. 1418(1), c = 2. 2908(3)nm, beta = 95. 08(1)degrees, V= 3. 749(1)nm(3), Z = 4. It has infinite 2-D network structures, and the 2-D networks are extended into 3-D network structures by packing along the a-axis through hydrogen bonding, exhibiting a certain inclusion phenomenon.

引用

页码：699 / 703

页数：5

共 16 条

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