Gadolinium potassium hexacyanoferrate(II) trihydrate

被引：7
|
作者：
Mullica, DF
Ward, JL
Sappenfield, EL
机构：
[1] Chemistry Department, Baylor University, Waco, TX 76798-7348
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷
关键词：
D O I：
10.1107/S0108270196010840
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gadolinium potassium hexacyanoferrate(II) trihydrate, GdKFe(CN)(6).3H(2)O, crystallizes in the orthorhombic space group Pnma (No. 62). The structure consists of non-linear cyanide bridges linking octahedrally coordinated Fe atoms and eight-coordinate Gd atoms. Cavities within the structure are occupied by potassium and zeolitic water molecules which are within hydrogen-bonding distance of the water molecules bonded to the Gd atoms, GdN6(H2O)(2).
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收藏
页码：2956 / 2959
页数：4
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