Effect of Temperature and Microwave Power Levels on Microwave Drying Kinetics of Zhaotong Lignite

被引:23
|
作者
Zhao, Pengfei [1 ,2 ]
Liu, Chenhui [1 ,2 ]
Qu, Wenwen [3 ]
He, Zhixiu [1 ,2 ]
Gao, Jiyun [1 ,2 ]
Jia, Lijuan [1 ,2 ]
Ji, Siping [1 ,2 ]
Ruan, Roger [4 ]
机构
[1] Yunnan Minzu Univ, Sch Chem & Environm, Key Lab Resource Clean Convers Ethn Reg, Educ Dept Yunnan Prov, Kunming 650500, Yunnan, Peoples R China
[2] Yunnan Minzu Univ, Key Lab Comprehens Utilizat Mineral Resources Eth, Kunming 650500, Yunnan, Peoples R China
[3] Kunming Univ Sci & Technol, Fac Sci, Kunming 650500, Yunnan, Peoples R China
[4] Univ Minnesota, Ctr Biorefining, Bioprod & Biosyst Engn Dept, St Paul, MN 55101 USA
基金
中国国家自然科学基金;
关键词
lignite; microwave drying kinetics; hot-air drying kinetics; effective diffusion coefficient; apparent activation energy; PHYSICOCHEMICAL PROPERTIES; FUNCTIONAL-GROUPS; XIMENG LIGNITE; PORE STRUCTURE; MODEL; WATER; MOISTURE; COAL;
D O I
10.3390/pr7020074
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Microwave drying is a promising and effective way to drying and upgrading lignite. The influence of temperature (100-140 degrees C) and microwave power levels (500-800 W) on thin-layer drying characteristics of Zhaotong lignite under microwave irradiation were investigated. Fourteen thin-layer drying models were used to analyze the microwave drying process while six thin-layer drying models were used to analyze the hot-air drying process. The microwave drying processes at all temperature (100-140 degrees C) or low microwave power levels (500-700 W) exhibited four periods: a warm-up period, a short constant period, the first and second falling rate period, while one falling rate period was found during hot-air drying. The effective diffusion coefficient of lignite were calculated and it increases with increasing temperature and microwave power levels. During microwave drying, the two-term exponential model is the most suitable model for all applied conditions, while the Modified Page model is the most suitable model to describe the hot-air drying experiments. The apparent activation energy were determined from Arrhenius equation and the values for the first and second falling rate period are 3.349 and 20.808 kJ.mol(-1) at different temperatures, while they are 13.455 and 19.580 Wg(-1) at different microwave power levels. This implies the apparent activation energy is higher during the second falling rate period, which suggest that the dewatering of absorbed water is more difficult than capillary water. The value of apparent activation energy in hot-air drying is between the first and second falling rate period of microwave drying. Results indicate that microwave drying is more suitable to dewatering free water and capillary water of lignite.
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页数:18
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