Measurement of Trace C2H6 Based on Optical-Feedback Cavity-Enhanced Absorption Spectroscopy

被引:1
|
作者
Wan Fu [1 ]
Chen Wei-gen [1 ]
Gu Zhao-liang [1 ]
Zou Jing-xin [1 ]
Du Ling-ling [1 ]
Qi Wei [1 ]
Zhou Qu [1 ]
机构
[1] Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Se, Chongqing 400044, Peoples R China
关键词
Cavity-enhanced absorption spectroscopy; Optical feedback; Ethane; Dissolved gas analysis; LASER;
D O I
10.3964/j.issn.1000-0593(2015)10-2792-05
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Ethane is one of major fault characteristic gases dissolved in power transformer, the detection of Ethane with high accuracy and sensitivity is the key of dissolved gas analysis. In this paper, based on optical feedback theory and cavity-enhanced absorption spectroscopy, combined with quantum cascade laser, a detection system for dissolved gas C2H6 in transformer oil was built up. Based on the symmetry of the individual cavity modes, the phase matching of returning light in resonance with the cavity was achieved through Lab VIEW codes. The optical feedback effect that the emitted light return to the laser cavity after a small delay time and lock to the resonance frequency of cavity, even and odd modes effect that the higher modes and lower modes structure will build up alternatively, and threshold current lowering effect of about 1.2 mA were studied and achieved. By cavity ring-down spectroscopy, the effective reflectivity of 99.978% and cavity finesse of 7 138.4 is obtained respectively. The frequency selectivity is 0.005 2 cm(-1). With an acquisition time of is, this optical system allows detection for the (P)Q(3) band of C-2 H-6 with high accuracy of 95.72%+/- 0.17% and detection limit of (1.97 +/- 0.06) X10(-3) mu L . L-1 at atmospheric pressure and temperature of 20 degrees C, which lays a foundation for fault diagnose from dissolved gas analysis.
引用
收藏
页码:2792 / 2796
页数:5
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