[3+2] cycloaddition of allylic silane with N-chlorosulfonyl isocyanate

被引：18

作者：

Isaka, M

Williard, PG

Nakamura, E

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[2] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1999年 / 72卷 / 09期

关键词：

D O I：

10.1246/bcsj.72.2115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of a substituted allylsilane with N-chlorosulfonyl isocyanate at 0 degrees C takes place in an unexpected manner to give a [3+2] cycloaddition product, a beta-silyl-gamma-lactam, rather than a [2+2] cycloadduct.

引用

页码：2115 / 2116

页数：2

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