C-C Cross-Coupling of Primary and Secondary Benzylic Alcohols Using Supported Gold-Based Bimetallic Catalysts

被引：58
|
作者：
Liu, Xiang [1 ]
Ding, Ran-Sheng [1 ]
He, Lin [1 ]
Liu, Yong-Mei [1 ]
Cao, Yong [1 ]
He, He-Yong [1 ]
Fan, Kang-Nian [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 04期
基金：
中国国家自然科学基金;
关键词：
alcohols; cross-coupling; gold; ketones; palladium; POT BETA-ALKYLATION; ALPHA-ALKYLATION; N-ALKYLATION; TRANSFER HYDROGENATION; BORROWING HYDROGEN; EFFICIENT; KETONES; COMPLEXES; IRIDIUM; NANOPARTICLES;
D O I：
10.1002/cssc.201200804
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Clean alcohol-alcohol cross-coupling: A clean and efficient one-pot direct C-C cross-coupling of equimolar amounts of primary and secondary alcohols by a facile hydrogen autotransfer pathway is achieved over a robust and easily recovered hydrotalcite-supported Au-Pd bimetallic catalyst system. A variety of primary and secondary alcohols have been selectively converted into the corresponding b-alkylated ketones in good yields. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：604 / 608
页数：5
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