The utilization of supercritical carbon dioxide in the palladium-catalyzed hydroarylation of β-substituted-α,β-enones

被引：0
|
作者：
Cacchi, S
Fabrizi, G
Gasparrini, F
Pace, P
Villani, C
机构：
[1] Univ La Sapienza, Dipartimento Studi Chim & Tecnol Sostanze Biologi, I-00185 Rome, Italy
[2] Univ G DAnnunzio, Dipartimento Sci Farmaco, I-66013 Chieti, Italy
来源：
SYNLETT | 2000年 / 05期
关键词：
supercritical carbon dioxide; palladium; catalysis; hydroarylation;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The utilization of supercritical carbon dioxide (scCO(2)) has a beneficial effect on the palladium-catalyzed reaction of acyclic beta-substituted-alpha,beta-enones with aryl iodides and hydroarylation (formal conjugate addition) products were isolated in good to high yields. The hydroarylation to vinylic substitution ratio is usually high.
引用
收藏
页码：650 / 652
页数：3
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