Synthesis and characterization of three novel ferromagnetic copper(II) binuclear complexes bridged by phthalato

被引：0
|
作者：
Ma, SL [1 ]
Zhang, LZ [1 ]
机构：
[1] Tianjin Univ Commerce, Dept Pharmaceut Engn, Tianjin 300134, Peoples R China
来源：
POLISH JOURNAL OF CHEMISTRY | 2002年 / 76卷 / 11期
关键词：
phthalate dianion bridge; copper(II)-copper(II) binuclear complex; ferromagnetic interaction;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three novel copper(II) binuclear complexes with phthalate dianion as bridging ligand have been obtained, namely [Cu-2(phth)(L)(4)](ClO4)(2), where phth denotes the phthalate dianion and L represents 1,10-phenanthroline (abbreviated as phen), 2,2'-bipyridine (bpy) or 4,4'-dimethyl-2,2'-bipyridine (Me(2)bpy). Meanwhile, the IR, electronic spectra, ESR spectra and the temperature-dependent magnetic susceptibility of the three complexes were analyzed. The results of the magnetic analyses show a weak ferromagnetic coupling between the paramagnetic ions in all complexes studied.
引用
收藏
页码：1537 / 1543
页数：7
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