Fluorometric sensing of Triton X-100 based organized media in water by a MOF

被引:4
|
作者
Dey, Biswajit [1 ]
Mondal, Ranjan Kumar [1 ]
Dhibar, Subhendu [1 ]
Chattopadhyay, Asoke Prasun [2 ]
Bhattacharya, Subhash Chandra [3 ]
机构
[1] Visva Bharati Univ, Dept Chem, Santini Ketan 731235, W Bengal, India
[2] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India
[3] Jadavpur Univ, Dept Chem, Kolkata 700032, India
关键词
Metal-organic-framework; Triton X-100; Sensor; Fluorescence; FESEM; GAUSSIAN-BASIS SETS; MICELLES; SOLUBILIZATION; CYCLODEXTRINS; ARSENIC(III); MEMBRANES; CRYSTAL; SENSOR; PROBE;
D O I
10.1016/j.jlumin.2015.10.075
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The fluorescent property of the aqueous solution of a metal organic framework (MOF) of Mn(II), having a sedimentary rocks like microstructure in solid-state, has been investigated. The luminescent feature of the the aqueous solution of MOF has been employed for studying the interactions of MOF with different surfactants including neutral, cationic, and anionic types in water medium. Interestingly, the MOF can very selective sense Triton X-100 based micelle in water medium. During the sensing process the fluorescent monomer of the MOF gets accommodated at the palisade layer of Triton X-100 in water medium and this has also been justified by simple fluorescence spectral and FE-SEM microstructural analysis. Thus, a MOF of Mn(II) can act as a selective fluorescent sensor for Triton X-100 based organized medium in water. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
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