Towards the identification of characteristic minor components from textiles dyed with weld (Reseda luteola L.) and those dyed with Mexican cochineal (Dactylopius coccus Costa)

被引:76
|
作者
Peggie, David A. [1 ,2 ]
Hulme, Alison N. [1 ]
McNab, Hamish [1 ]
Quye, Anita [2 ]
机构
[1] Univ Edinburgh, Sch Chem, Edinburgh, Midlothian, Scotland
[2] Natl Museums Scotland, Conservat & Analyt Res Dept, Edinburgh, Midlothian, Scotland
关键词
natural dyes; flavonoids; anthraquinones; historical textiles;
D O I
10.1007/s00604-007-0866-0
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The identity of a minor flavonoid component observed in extracts of textile samples dyed with weld (Reseda luteola L.) is confirmed as chrysoeriol (3'-O-methylluteolin) by HPLC-PDA analysis. HPLC-PDA, HPLC-MS and NMR techniques have been used to show that the unknown dcII component found in extracts of textiles dyed with Mexican cochineal (Dactylopius coccus Costa) is most probably the 7-C-glycoside of flavokermesic acid. In addition, the unknown dcIV and dcVII components have been shown to be isomeric with carminic acid, most probably differing only in the stereochemistry of the sugar moiety.
引用
收藏
页码:371 / 380
页数:10
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