[2+2] Cycloaddition reaction as a tool to monitor the formation of thermodynamically stable ladder coordination polymers

被引：18

作者：

Chanthapally, Anjana ^{[1
]}

Oh, Wei Ting ^{[1
]}

Vittal, Jagadese J. ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 45期

关键词：

SOLID-STATE; STRUCTURAL TRANSFORMATIONS; CONVERSION; NETWORK;

D O I：

10.1039/c3ce41176a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A linear Cu(II) coordination polymer was transformed to a sheet or ladder structure by the loss of coordinated DMF when the single crystals or the ground powder, respectively, were used. Further, the sheet structure rearranged to a ladder polymer when the desolvated single crystals were ground to powder, as monitored by H-1-NMR spectroscopy.

引用

页码：9324 / 9327

页数：4

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