Targeted Synthesis of a prototype MOF Based on Zn4(O)(O2C)6 Units and a Nonlinear Dicarboxylate Ligand

被引：65
|
作者：
Chun, Hyungphil [1 ]
Jung, Heejin [1 ]
机构：
[1] Hanyang Univ, Coll Sci & Technol, Dept Appl Chem, Ansan 426791, South Korea
来源：
INORGANIC CHEMISTRY | 2009年 / 48卷 / 02期
关键词：
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; ADSORPTION; SORPTION; NETS; MICROPOROSITY; CATENATION; TOPOLOGY; BINDING; MOTIFS;
D O I：
10.1021/ic801906e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A surprisingly small number of topologies are known in metal-organic frameworks (MOFs) that possess Zn-4(O)(O2C)(6) building units. One of such MOFs having a simple, nonlinear dicarboxylate ligand, 5-methylisophthalate (mip), is targeted and successfully synthesized. The framework, [Zn-4(O)(mip)(3)], is based on a nonuniform, uninodal six-connected net and is featured by complicated meshlike pores with narrow passages. Gas sorption studies reveal the potentials as a prototype from which new MOFs having interesting properties can be derived.
引用
收藏
页码：417 / 419
页数：3
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