New fluorescent switches based on photochromic 2,3-diarylcyclopent-2-en-1-ones and 6-ethoxy-3-methyl-1H-phenalen-1-one

被引：30

作者：

Lonshakov, Dmitry V. ^{[1
]}

Shirinian, Valerii Z. ^{[1
]}

Lvov, Andrey G. ^{[1
]}

Nabatov, Boris V. ^{[2
]}

Krayushkin, Mikhail M. ^{[1
]}

机构：

[1] ND Zelinsky Inst Organ Chem RAS, Moscow 119991, Russia

[2] AV Shubnikov Inst Crystallog RAS, Moscow 119333, Russia

来源：

DYES AND PIGMENTS | 2013年 / 97卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

Photochromic diarylethenes; Fluorescent switches; 2,3-diarylcyclopent-2-en-1-ones; Fluorophore; Fluorescence resonance energy transfer; Thiophene; ENERGY; MOLECULES;

D O I：

10.1016/j.dyepig.2012.12.019

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

New fluorescent switches with 2,3-diarylcyclopent-2-en-1-ones as the photochromic component and 6-ethoxy-3-methyl-1H-phenalen-1-one as the fluorophore have been prepared. Two approaches to develop the photoswitches have been applied. The first involves covalent binding of the fluorophore to photochromic diarylethene molecule by ether linkage. The second type of fluorescent switch was been prepared by the blending of the photochromic 2,3-diarylcyclopent-2-en-1-ones and 6-ethoxy-3-methyl-1H-phenalen-1-one in various ratios. The spectral properties of fluorescent switches have been investigated and possible ways of fluorescence quenching are discussed. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：311 / 317

页数：7

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