A facile and one-pot electrochemical method for the synthesis of a new anthraquinonethioether

被引：3
|
作者：
Nematollahi, Davood [1 ]
Moradi, Bayan [2 ]
Varrnaghani, Fahimeh [1 ]
机构：
[1] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran
[2] Islamic Azad Univ, Arak Branch, Fac Sci, Dept Chem, Arak, Iran
来源：
CHINESE CHEMICAL LETTERS | 2012年 / 23卷 / 05期
关键词：
1,4-Dihydroxyanthraquinone; 2-Mercaptobenzothiazole; Electrochemical synthesis; Anthraquinonethioether; Cyclic voltammetry; Digital simulation; OXIDATION; DERIVATIVES;
D O I：
10.1016/j.cclet.2012.03.018
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of electrochemically generated anthradiquinone as a Michael acceptor with 2-mercaptobenzothiazole and 2-mercaptobenzoxazole, as nucleophiles in ethanol/water mixtures has been studied by means of cyclic voltammetry. Our voltammetric data indicate that produced anthradiquinone participates in Michael addition reaction with nucleophiles and via an ECEC mechanism converts to the new anthraquinonethioether derivatives. Based on an EC mechanism, the observed homogeneous rate constant of the Michael reaction of anthradiquinone with nucleophiles were estimated by comparing the experimental cyclic voltammograms with the digital simulated results. (C) 2012 Davood Nematollahi. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：553 / 556
页数：4
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