Hydrothermal synthesis and crystal structure of a layered coordination polymer:: [Zn3(C2O4)3(4,4′-bipy)4]n (4,4′-bipy=4,4′-bipyridine)

被引：21
|
作者：
Hao, N [1 ]
Shen, EH [1 ]
Li, YG [1 ]
Wang, EB [1 ]
Hu, CW [1 ]
Xu, L [1 ]
机构：
[1] NE Normal Univ, Inst Polyoxometalate Chem, Dept Chem, Changchun 130024, Jilin, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 691卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
coordination polymer; metal-organic; hydrothermal synthesis; crystal structure;
D O I：
10.1016/j.molstruc.2004.01.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An interesting metal-organic coordination polymer {[Zn-3(C2O4)(3)(4,4'-bipy)(4)]}(n) 1 has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, TG analysis, and single-crystal X-ray diffraction. Compound I crystallizes in the monoclinic system, space group P2(1)/c, a = 16.264(3) Angstrom, b = 15.603(3) Angstrom, c = 16.343(3) Angstrom, beta = 94.13(3)degrees, V = 4136.5(14) Angstrom(3), Z = 4, R1 = 0.0554, wR(2) = 0.1217. Compound 1 exhibits a 2D network, which consists of infinite zinc (II) oxalate chains connected to each other by a half of 4,4'-bipy acting as bridging ligands, while the other half of 4,4-bipy just does as terminal ones. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：273 / 277
页数：5
相关论文
共 50 条
  • [1] Mechanochemical Synthesis of [Zn3(C2O4)3(4,4′-bipy)4] and its Reorganization at High Temperatures
    Troebs, Lisa
    Zimathies, Annett
    Panne, Ulrich
    Emmerling, Franziska
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2014, 228 (4-5): : 575 - 585
  • [2] Sonochemical synthesis and characterization of a nano-sized Manganese (II) coordination polymer, [{Mn(NCS)(2)(4,4 ' -bipy)(H2O)(2)}(4,4 ' - bipy)](n); with 4,4 '-Bipyridine (4,4 '-bipy) ligand
    Mosallanejad, N.
    INTERNATIONAL JOURNAL OF NANO DIMENSION, 2014, 5 (03) : 285 - 289
  • [3] A new one-dimensional 4,4′-bipy-bridged compound [Mn(hfac)2(4,4′-bipy)]n (hfac = hexafluoroacetetylacetonato;: 4,4′-bipy = 4,4′-bipyridine).: Synthesis, crystal structure and magnetic properties
    Shen, HY
    Liao, DZ
    Jiang, ZH
    Yan, SP
    Sun, BW
    Wang, GL
    Yao, XK
    Wang, HG
    POLYHEDRON, 1998, 17 (11-12) : 1953 - 1957
  • [4] Hydrothermal synthesis and crystal structure of a novel 4,4′-bipyridine bridging dumbbell-like dimeric pentamolybdate:: [4,4′-H2bipy]3[4,4′-Hbipy]2[(Mo5O17)2(4,4′-bipy)]
    Niu, JY
    Wang, ZL
    Wang, JP
    INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (04) : 556 - 558
  • [5] Thermal and structural studies of a 1D zinc(II) coordination polymer -: [Zn(μ-4,4′-bipy)(H2O)4]n(CCl3COO)2n•(4,4′-bipy)2n (4,4′-bipy=4,4′-bipyridine), with shorted Cl • • • Cl interactions
    Amiri, Maryam Ghoreishi
    Morsali, Ali
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (8-9): : 1419 - 1421
  • [6] The synthesis and crystal structure {[Co(4,4′-bipy)(ambdc)(H2O)2](4,4′-bipy)(DMF)}n
    He, HY
    Zhou, YL
    Zhu, LG
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (01) : 142 - 144
  • [7] Structural, thermal, and magnetic properties of three transition metal-4,4′-bipyridine coordination polymers:: [Ni(4,4′-bipy)3(H2O)2](ClO4)2•1.4(4,4′-bipy)•3(H2O); [Co(4,4′-bipy)3(H2O)2](ClO4)2•1.4(4,4′-bipy)•3(H2O); [Cu(4,4′-bipy)3(DMSO)2](ClO4)2•2(4,4′-bipy)
    Woodward, JD
    Backov, R
    Abboud, KA
    Ohnuki, H
    Meisel, MW
    Talham, DR
    POLYHEDRON, 2003, 22 (20) : 2821 - 2830
  • [8] Hydrothermal Synthesis,Crystal Structure and Characterization of a New Keggin Polyoxometalate {[AgI(4,4’-bipy)]3[PW12O40]}·(4,4’-bipy)
    余友谊
    陈建新
    柯志聪
    胡丽姗
    余颖华
    林欣蓉
    张治纯
    Chinese Journal of Structural Chemistry, 2011, 30 (03) : 362 - 367
  • [9] Hydrothermal Synthesis, Crystal Structure and Characterization of a New Keggin Polyoxometalate {[AgI(4,4′-bipy)]3[PW12O40]}•(4,4′-bipy)
    Yu You-Yi
    Chen Jian-Xin
    Ke Zhi-Cong
    Hu Li-Shan
    Yu Ying-Hua
    Lin Xin-Rong
    Zhang Zhi-Chun
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 30 (03) : 362 - 367
  • [10] Syntheses, crystal structures and magnetic properties of two novel layered compounds:: [Fe3(C2O4)3(4,4′-bpy)4] and [Co(C2O4)-(4,4′-bpy)] (4,4′-bpy=4,4′-bipyridine)
    Zheng, LM
    Fang, X
    Lii, KH
    Song, HH
    Xin, XQ
    Fun, HK
    Chinnakali, K
    Razak, IA
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (14): : 2311 - 2316
12345