Enantioselective total syntheses of 13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one

被引：6

作者：

Li, AP

Bie, PY

Peng, XS

Wu, TX

Pan, XF ^{[1
]}

Chan, ASC

Yang, TK

机构：

[1] Lanzhou Univ, Dept Chem, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

[3] Hong Kong Polytech Univ, Union Lab Asymmetry Synth, Hong Kong, Hong Kong, Peoples R China

[4] Natl Chunghsing Univ, Dept Chem, Taichung 40227, Taiwan

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 04期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1081/SCC-120002407

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A enantioselective total synthetic route to (+)-13-acteyl-12-hydroxy-podocarpane-8,11,13-triene-7-one la and (-)-13-acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one 1b from (S)-(-)-alpha-cyclocitral 8a and (R)-(+)-alpha-cyclocitral 8b was developed.

引用

页码：605 / 610

页数：6

共 25 条

[1] Chiral Synthesis of 13-Acetyl-12-hydroxy-podocarpane-8,11,13-triene-7-one
An Pai LI
ChineseChemicalLetters, 2001, (03) : 205 - 206
[2] Chiral synthesis of 13-acetyl-12-hydroxy-podocarpane-8, 11,13-triene-7-one
Li, AP
Gan, YH
Peng, XS
Wu, TX
Pan, XF
CHINESE CHEMICAL LETTERS, 2001, 12 (03) : 205 - 206
[3] FORMYLATION ON 12-HYDROXY-13-METHYLPODOCARPA-8,11,13-TRIENE - STERIC INHIBITION TO IMINE HYDROLYSIS
CHATTERJEE, S
GHOSAL, PK
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1979, 18 (02): : 187 - 188
[4] Oxidations of 12-deoxy-, 12-hydroxy-, 12-methoxy-, and 12-hydroxy-13-methoxy-podocarpa-8,11,13-triene derivatives
Cambie, RC
Costa, MD
Kong, NN
Lu, HT
Metzler, MR
Rickard, CEF
Rutledge, PS
Woodgate, PD
AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (01) : 37 - 47
[5] Facile access to optically active ring C aromatic diterpene derivatives from manool.: Highly efficient syntheses of (+)-12-methyl-7-oxopodocarpa-8,11,13-triene-13-carboxylic acid, (+)-13-methyl-7-oxopodocarpa-8,11,13-triene-12-carboxylic acid and (+)-nimbiol
Nakano, T
Alonso, R
Maillo, MA
Martín, A
Núñez, RA
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (08): : 1423 - 1426
[6] Facile access to optically active ring C aromatic diterpene derivatives from manool. Highly efficient syntheses of (+)-12-methyl-7-oxopodocarpa-8,11,13-triene- 13-carboxylic acid, (+)-13-methyl-7-oxopodocarpa-8,11,13-triene- 12-carboxylic acid and (+)-nimbiol
J Chem Soc Perkin Trans 1, 8 (1423):
[7] SYNTHESIS OF (+/-)-13-ACETYL-12-HYDROXYPODOCARPA-8,11,13-TRIEN-7-ONE AND RELATED-COMPOUNDS - NONCONFORMITY WITH THE ASSIGNED STRUCTURE OF NIMBOSODIONE
GHOSH, S
GHATAK, UR
JOURNAL OF CHEMICAL RESEARCH-S, 1992, (10): : 352 - 353
[8] TOTAL SYNTHESIS OF (+/-)-12-METHOXYABIETA-8,11,13-TRIEN-6-ONE, A VERSATILE INTERMEDIATE FOR DITERPENE SYNTHESES
BANERJEE, AK
DECARRASCO, MCS
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (01): : 25 - 31
[9] A FACILE ACCESS TO OPTICALLY-ACTIVE RING-C AROMATIC DITERPENE DERIVATIVES - HIGHLY EFFICIENT SYNTHESIS OF (+)-12-METHYL-7-OXOPODOCARPA-8,11,13-TRIENE-13-CARBOXYLIC ACID AND (+)-13-METHYL-7-OXOPODOCARPA-8,11,13-TRIENE-12-CARBOXYLIC ACID FROM MANOOL
NAKANO, T
ALONSO, R
MAILLO, MA
MARTIN, A
NUNEZ, RA
TETRAHEDRON LETTERS, 1995, 36 (22) : 3801 - 3804
[10] First Total Synthesis of 12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one
Cheng Lu ZHANG
Chinese Chemical Letters, 2006, (02) : 163 - 164

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