Electric forces effect on field-assisted sintering

被引:7
|
作者
Biesuz, Mattia [1 ]
Sglavo, Vincenzo M. [1 ]
机构
[1] Univ Trento, Dept Ind Engn, Via Sommar 9, I-38123 Trento, Italy
关键词
Flash sintering; Field assisted sintering; Spark plasma sintering; Sintering; Electric force; DENSIFICATION MECHANISMS; LATTICE EXPANSION; THERMAL RUNAWAY; HEATING RATE; FLASH; TEMPERATURE; CERAMICS; ZIRCONIA; CERIA; PHOTOEMISSION;
D O I
10.1016/j.jeurceramsoc.2020.06.069
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Electric forces acting on crystallographic defects generated at the flash onset or due to the surface polarization of the dielectric surrounding pores have been claimed to interact with the sintering kinetics upon flash processes. Herein, we estimated the magnitude of the external field-induced forces pointing out that the surface polarization does not play significant role on sintering. Moreover, the electric forces acting on charged defects are negligible when compared with the sintering stresses in the majority of flash experiments, only becoming comparable with the capillarity pressures when the external field is in the order of 103 V cm(-1). Therefore, they can be of some relevance during flash sintering of resistive compounds like alumina or silicate glasses, they remaining normally not relevant otherwise.
引用
收藏
页码:6259 / 6265
页数:7
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