Preparation and properties of stabilized thioxophosphine sulfides bearing the 4-t-butyl-2,6-bis(dialkylaminomethyl)phenyl or the 2,4-di-t-butyl-6-(dialkylaminomethyl)phenyl substituents

被引:11
|
作者
Kamijo, K [1 ]
Otoguro, A [1 ]
Toyota, K [1 ]
Yoshifuji, M [1 ]
机构
[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan
关键词
D O I
10.1246/bcsj.72.1335
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Stabilized thioxophosphine sulfides bearing the 4-t-butyl-2,6-bis(dialkylaminomethyl)phenyl or the 2,4-di-t-butyl-6-(dialkylaminomethyl)phenyl group, as well as their N-15 labeled analogs, were prepared. Intramolecular interaction between the nitrogen and the phosphorus atoms was investigated, mainly by means of P-31 NMR and H-1 NMR spectroscopic studies.
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页码:1335 / 1342
页数:8
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