Carboxylate-substituted Ti(IV) oxo clusters with a Ti3O core

被引：8
|
作者：
Czakler, Matthias [1 ]
Schubert, Ulrich [1 ]
机构：
[1] Vienna Univ Technol, Inst Mat Chem, Getreidemarkt 9, A-1060 Vienna, Austria
来源：
INORGANICA CHIMICA ACTA | 2018年 / 471卷
基金：
奥地利科学基金会;
关键词：
Metal oxo clusters; Titanium compounds; Carboxylate ligands; X-ray structure analyses; UNEXPECTED FORMATION; TITANIUM ALKOXIDES;
D O I：
10.1016/j.ica.2017.11.055
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ti3O(OiPr)(6)(OOC-adamantyl)(4) and Ti3O2(OiPr)(3)(OOCCPh3)(5) were obtained from the reaction of Ti(OiPr)(4) with adamantylcarboxylic or triphenylacetic acid, respectively. The structures of both are based on a central Ti3O unit, which is substituted by different numbers of bridging carboxylate ligands and, in the case of the adamantyl derivative, also a chelating one. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：567 / 569
页数：3
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