A catalytic enantioselective electron transfer reaction:: Titanocene-catalyzed enantioselective formation of radicals from meso-epoxides

被引：0
|
作者：
Gansäuer, A
Lauterbach, T
Bluhm, H
Noltemeyer, M
机构：
[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany
[2] Univ Gottingen, Inst Anorgan Chem, D-3400 Gottingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 19期
关键词：
enantioselectivity; epoxides; homogeneous catalysis; radical reactions; titanium;
D O I：
10.1002/(SICI)1521-3773(19991004)38:19<2909::AID-ANIE2909>3.0.CO;2-Y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A rationally designed titanium(III) catalyst allows the opening of epoxides with. high enantioselectivity. This reaction [Eq. (1)] constitutes the first example of an enantioselective transition metal catalyzed radical reaction that proceeds by electron transfer.
引用
收藏
页码：2909 / 2910
页数：2
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