Carborane tuning of photophysical properties of phosphorescent iridium(III) complexes

被引：97
|
作者：
Shi, Chao [1 ]
Sun, Huibin [2 ,3 ]
Jiang, Qibai [1 ]
Zhao, Qiang [2 ,3 ]
Wang, Jingxia [2 ,3 ]
Huang, Wei [2 ,3 ]
Yan, Hong [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ Posts & Telecommun, Key Lab Organ Elect & Informat Displays, Nanjing 210046, Jiangsu, Peoples R China
[3] Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210046, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 42期
基金：
中国国家自然科学基金;
关键词：
ORGANIC ELECTROPHOSPHORESCENCE; EMITTING DEVICES; METAL-COMPLEXES; O-CARBORANE; BLUE; EMISSION; LIGANDS; SENSOR;
D O I：
10.1039/c3cc40996a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Both neutral and cationic iridium(III) complexes containing carborane units were synthesized. Bulky carboranes can significantly improve phosphorescence quantum yields of these complexes and the electronic effect of carboranes can evidently tune emission wavelengths of cationic complexes.
引用
收藏
页码：4746 / 4748
页数：3
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