New organocobaloximes with biphenylglyoxime ligands: Synthesis, spectroscopic and structural characterization

被引：1
|
作者：
Erdem-Tuncmen, Mukadder [1 ]
Karipcin, Fatma [2 ]
机构：
[1] Suleyman Demirel Univ, Sci & Arts Fac, Dept Chem, TR-32260 Isparta, Turkey
[2] Nevsehir Haci Bektas Veli Univ, Dept Chem, Sci & Arts Fac, Nevsehir, Turkey
来源：
MAIN GROUP CHEMISTRY | 2014年 / 13卷 / 01期
关键词：
Organocobaloxime; thermal analyses; dioxime; cobalt; COBALT(III) COMPLEXES; METAL-COMPLEXES; COBALOXIMES; DIOXIME; CU(II); MODELS; ALKYL;
D O I：
10.3233/MGC-140124
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New organocobaloximes of the types, [RCo(HL)(2)H2O] and [RCo(HL)(2)APy] (R= izopropyl and benzyl, H2L1= 4(4-chlorophenylamino)biphenylglyoxime, H2L2 = 4-(naphtyl-1-amino) biphenylglyoxime, APy= 2-acetyl pyridine) have been synthesized and characterized by elemental analysis, magnetic susceptibility, molar conductivity, H-1-NMR, FT-IR, ICP-OES data. In addition, the thermal decomposition of complexes with H2L2 was studied in nitrogen atmosphere. The magnetic susceptibilities of the complexes indicated that they are diamagnetic (low-spin d(6) octahedral).
引用
收藏
页码：73 / 84
页数：12
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