Synthesis and Molecular Structures of BINOL Complexes: An STM Investigation of 2D Self-Assembly

被引:6
|
作者
Zeng, Xianghua [1 ]
Chang, Shaoqing [2 ,3 ]
Deng, Ke [2 ]
Zhang, Junyong [1 ]
Sun, Hongbin [3 ]
Zeng, Qingdao [2 ]
Xie, Jingli [1 ,4 ]
机构
[1] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China
[2] Natl Ctr Nanosci & Technol NCNST, CAS Key Lab Standardizat & Measurement Nanotechno, Beijing 100190, Peoples R China
[3] Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Peoples R China
[4] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
BONDED ORGANIC FRAMEWORK; SEPARATION; NETWORKS;
D O I
10.1021/acs.cgd.5b00143
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three new (R)-BINOL complexes have been prepared. 2D self-assembly has been observed in the system consisting of crystalline (R)-BINOL derivatives (guest) and 1,3,5-tris(10-carboxydecyloxy)-benzene (host) by means of the scanning tunneling microscopy (STM) technique. Density functional theory (DFT) calculations help to reveal the assembly on the HOPG surface.
引用
收藏
页码:3096 / 3100
页数:5
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