Nanohybrid catalysts with porous structures for environmental remediation through photocatalytic degradation of emerging pollutants

Water supplies have been seriously challenged by new emerging pollutants, which are difficult to remove by traditional wastewater treatment. Thus, new technologies such as catalytic advanced oxidation processes have merged as suitable solutions; however, the drawbacks of typical catalysts limit their application. To overcome this issue, new materials with enhanced textural properties have been developed, showing that their porosity and chemical nature influence their potential as a catalyst. Herein, the recent progress in highly porous catalysts and their suitable deployment to effectively nano-remediate the polluted environmental matrices are reviewed in detail. First, following a brief introduction, several environmental pollutants of emerging concerns from different sectors, including pharmaceutical residues, endocrine-disrupting chemicals (EDCs), pesticides, and hazardous dyes are also introduced with relevant examples. To effectively tackle the sustainable remediation of emerging pollutants, this work also focuses on the multifunctional features of nanohybrid porous materials that act as catalysts constructs to degrade emerging pollutants. The influence of surface reactive centers, stability, bandgap energies, light absorption capacities, and pollutants adsorption capacities are also discussed. Successful examples of the employment of nanohybrid porous catalysts for the degradation of pharmaceutical pollutants, EDCs, pesticides, and hazardous dyes are summarized. Finally, some challenges faced by nanohybrid porous materials to achieve their potential application as advanced catalysts for environmental remediation have been identified and presented herein.