Boron-Doped Diamond Electrodes for Electroorganic Chemistry

被引：66
|
作者：
Waldvogel, Siegfried R. [1 ]
Mentizi, Stamo [1 ]
Kirste, Axel [2 ]
机构：
[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55128 Mainz, Germany
[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
来源：
RADICALS IN SYNTHESIS III | 2012年 / 320卷
关键词：
Anode; Boron-doped diamond; Cathode; Electrochemistry; Electrosynthesis; ASYMMETRIC CONJUGATE ADDITION; CROSS-COUPLING REACTIONS; ANODIC-OXIDATION; ELECTROCHEMICAL OXIDATION; PAIRED ELECTROLYSIS; CURRENT-DENSITY; POLYMER BEADS; RADICALS; HYDROGEN; PHENOL;
D O I：
10.1007/128_2011_125
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Boron-doped diamond (BDD) electrodes provide an unusually wide electrochemical window in protic media, since there exist large offset potentials for the evolution of molecular hydrogen and oxygen, respectively. At the anode, alcohols are specifically converted to alkoxyl radicals. These can be used for chemical synthesis. When the enormous reactivity of such intermediate spin centers is not controlled, mineralization or electrochemical incineration dominates. Efficient strategies include either high substrate concentrations or fluorinated alcohols which seem to stabilize the spin centers in the course of reaction.
引用
收藏
页码：1 / 31
页数：31
相关论文
共 50 条
  • [1] Charge transfer at boron-doped diamond electrodes
    Vinokur, N
    Miller, B
    Avyigal, Y
    Kalish, R
    [J]. PROCEEDINGS OF THE FIFTH INTERNATIONAL SYMPOSIUM ON DIAMOND MATERIALS, 1998, 97 (32): : 267 - 274
  • [2] Electrochemical studies of boron-doped diamond electrodes
    Argoitia, A
    Martin, HB
    Rozak, EJ
    Landau, U
    Angus, JC
    [J]. DIAMOND FOR ELECTRONIC APPLICATIONS, 1996, 416 : 349 - 354
  • [3] Uranium electrodeposition at boron-doped diamond electrodes
    Acevedo-Gonzalez, Alexis J.
    Pena-Duarte, Armando
    Lagle, Richard M.
    Drabo, Mebougna
    Jones, Andrew C.
    Cabrera, Carlos R.
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2024, 54 (11) : 2577 - 2593
  • [4] Electrochemical behavior of boron-doped diamond electrodes
    Vinokur, N
    Miller, B
    Avyigal, Y
    Kalish, R
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (10) : L238 - L240
  • [5] Electrochemical behavior of boron-doped diamond electrodes
    Vinokur, N
    Miller, B
    Avyigal, Y
    Kalish, R
    [J]. PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON NEW DIRECTIONS IN ELECTROANALYTICAL CHEMISTRY, 1996, 96 (09): : 149 - 158
  • [6] Electrogenerated chemiluminescence at boron-doped diamond electrodes
    Fiorani, Andrea
    Valenti, Giovanni
    Paolucci, Francesco
    Einaga, Yasuaki
    [J]. CHEMICAL COMMUNICATIONS, 2023, 59 (51) : 7900 - 7910
  • [7] Boron-doped graphene and boron-doped diamond electrodes: detection of biomarkers and resistance to fouling
    Tan, Shu Min
    Poh, Hwee Ling
    Sofer, Zdenek
    Pumera, Martin
    [J]. ANALYST, 2013, 138 (17) : 4885 - 4891
  • [8] Boron-doped diamond thin-film electrodes
    Xu, JS
    Granger, MC
    Chen, QY
    Strojek, JW
    Lister, TE
    Swain, GM
    [J]. ANALYTICAL CHEMISTRY, 1997, 69 (19) : A591 - A597
  • [9] Electrogeneration of hydroxyl radicals on boron-doped diamond electrodes
    Marselli, B
    Garcia-Gomez, J
    Michaud, PA
    Rodrigo, MA
    Comninellis, C
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (03) : D79 - D83
  • [10] Electroanalysis of Pharmaceuticals on Boron-Doped Diamond Electrodes: A Review
    Sousa, Camila P.
    Ribeiro, Francisco W. P.
    Oliveira, Thiago M. B. F.
    Salazar-Banda, Giancarlo R.
    de Lima-Neto, Pedro
    Morais, Simone
    Correia, Adriana N.
    [J]. CHEMELECTROCHEM, 2019, 6 (09) : 2350 - 2378
12345