A novel 4 • 82 CdII network constructed from helical motif:: Incorporating alternate left- and right-hand helical water chains

被引：22

作者：

Zhang, Meili ^{[1
]}

Li, Dongsheng ^{[1
]}

Fu, Feng ^{[1
,2
]}

Yang, Xiaogang ^{[1
]}

Wu, Yapan ^{[1
]}

Wang, Enbo ^{[2
]}

机构：

[1] Yanan Univ, Dept Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Shaanxi, Peoples R China

[2] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Cd-II network; crystal structure; helix; water chain; luminescence;

D O I：

10.1016/j.inoche.2008.04.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 2D 4 . 8(2) Cd-II network with alternating heterochiral motif was reported, which is extended to 3D through pi-pi stacking. Interestingly, 1 D hydrophilic tunnel of 3D architecture, providing potential helical hydrogen-bonded identification sites, acts as a template for the formation of the alternate left- and right-handed 1D helical water chains. The compound exhibits intense photoluminescence at room temperature. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：958 / 960

页数：3

共 14 条

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