Cationic Polymerization of 1,3-Pentadiene in Presence of AlCl3/SbCl3

被引：2
|
作者：
Wang, G. Q. [1 ]
Zhang, W. X. [1 ]
Liang, J. C. [1 ]
Chen, G. Y. [1 ]
Wei, Z. Y. [1 ]
Zhang, Long [2 ]
机构：
[1] Dalian Sci & Technol Univ, Coll Automot Engn, Dalian 116024, Peoples R China
[2] Changchun Univ Technol, Sch Chem Engn, Changchun 130012, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 05期
关键词：
Cationic polymerization; 1,3-Pentadiene; ALPHA-PINENE; BINARY CATALYSTS; CHLORIDE;
D O I：
10.14233/ajchem.2013.13667
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The cationic polymerization of 1,3-pentadiene using AlCl2/SbCl3 binary catalyst mainly carried out at various SbCl3 concentrations. With an increase in the SbCl3 concentration, the molecular weight decreased and molecular mass distribution of the polymer widened, that is consistent with beta-pinene. It is shown that the degree of unsaturation of poly(1,3-pentadiene) are almost independent of the SbCl3 concentrations.
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页码：2690 / 2692
页数：3
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