PP/PMMA block copolymers by combination of ATRP and metallocene catalysis

被引：0
|
作者：
Dix, A [1 ]
Ptacek, S [1 ]
Poser, S [1 ]
Arnold, M [1 ]
机构：
[1] Univ Halle Wittenberg, Inst Tech & Macromol Chem, D-06090 Halle, Germany
来源：
MACROMOLECULAR SYMPOSIA | 2006年 / 236卷
关键词：
ATRP; block copolymers; metallocene catalysis; poly(methyl methacrylate); poly(propylene);
D O I：
10.1002/masy.200690054
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
PP-b-PMMA has been synthesized by a combination of metallocene catalysis and the controlled radical polymerization technique ATRP. Cp2ZrCl2/MAO and (Me4CP)SiMe2(N-tert-Bu)TiCl2/MAO were used for the synthesis of atactic polypropylene. By a series of chemical modifications pp macroinitiators for the ATRP polymerization of MMA were synthesized. The PP-b-PMMA with polydispersities from 1.8-2.8 and an M-n ranging from 8 to 26 kg/mol was characterized by H-1-NMR,SEC and DSC.
引用
收藏
页码：186 / 192
页数：7
相关论文
共 50 条
  • [1] A novel synthesis of PP-b-PMMA copolymers via metallocene catalysis and borane chemistry
    Chung, TC
    Lu, HL
    Janvikul, W
    POLYMER, 1997, 38 (06) : 1495 - 1502
  • [2] Photoresponsive Azopolyester-PMMA Block Copolymers Obtained by Combination of ATRP, Polycondensation, and "Click" Chemistry
    Berges, Cristina
    Javakhishvili, Irakli
    Hvilsted, Soren
    Sanchez, Carlos
    Alcala, Rafael
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2012, 213 (21) : 2299 - 2310
  • [3] On the Cascade Polymerization Process Consisting of Metallocene Polymerization and ATRP to Prepare i-PP-Based Polar Block Copolymers
    Yi, Qingfeng
    Fan, Guoqiang
    Wen, Xiaojing
    Dong, Jin-Yong
    Han, Charles C.
    MACROMOLECULAR REACTION ENGINEERING, 2009, 3 (2-3) : 91 - 100
  • [4] Synthesis of block copolymers by combination of ATRP and photoiniferter processes
    Durmaz, Yasemin Yuksel
    Karagoz, Bunyamin
    Bicak, Niyazi
    Yagci, Yusuf
    POLYMER INTERNATIONAL, 2008, 57 (10) : 1182 - 1187
  • [5] Catenated PS-PMMA Block Copolymers via Supramolecularly Templated ATRP Initiator Approach
    Bunha, Ajay Kumar
    Mangadlao, Joey
    Felipe, Mary Jane
    Pangilinan, Katrina
    Advincula, Rigoberto
    MACROMOLECULAR RAPID COMMUNICATIONS, 2012, 33 (14) : 1214 - 1219
  • [6] Polychloroalkanes as ATRP initiators: Application to the synthesis of block copolymers from the combination of conventional radical polymerization and ATRP.
    Destarac, M
    Boutevin, B
    Matyjaszewski, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U480 - U481
  • [7] Polychloroalkanes as ATRP initiators. Application to the synthesis of block copolymers from the combination of conventional radical polymerization and ATRP
    Destarac, M.
    Boutevin, B.
    Matyjaszewski, K.
    American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, 1999, 40 (02): : 338 - 339
  • [8] Polymers and block copolymers of fluorostyrenes by ATRP
    Hvilsted, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U395 - U395
  • [9] Synthesis of PMMA-b-PU-b-PMMA tri-block copolymers through ARGET ATRP in the presence of air
    Krol, P.
    Chmielarz, P.
    EXPRESS POLYMER LETTERS, 2013, 7 (03): : 249 - 260
  • [10] Defined synthesis of copolymers using metallocene catalysis
    Kaminsky, W
    Schupfner, G
    MACROMOLECULAR SYMPOSIA, 2002, 177 : 61 - 69
12345