Hydrodeoxygenation of Vegetable Oil on NiMoS/WO3-Al2O3 Catalysts

被引：16

作者：

Nepomnyashchiy, A. A. ^{[1
]}

Buluchevskiy, E. A. ^{[1
,2
]}

Lavrenov, A. V. ^{[1
]}

Yurpalov, V. L. ^{[1
]}

Gulyaeva, T. I. ^{[1
]}

Leont'eva, N. N. ^{[1
]}

Talzi, V. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Hydrocarbons Proc, Siberian Branch, Ul Neftezavodskaya 54, Omsk 644040, Russia

[2] Omsk FM Dostoevsky State Univ, Ul Neftezavodskaya 11, Omsk 644053, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2017年 / 90卷 / 12期

关键词：

HIGH-QUALITY DIESEL; SOYBEAN OIL; GREEN DIESEL; FATTY-ACIDS; PALM OIL; BIFUNCTIONAL CATALYSTS; NATURAL TRIGLYCERIDES; STEP HYDROTREATMENT; HYDROCARBON FUELS; METHYL LAURATE;

D O I：

10.1134/S1070427217120084

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Tungstate-containing aluminum oxide is suitable as a catalyst support for hydrodeoxygenation of sunflower oil, ensuring 81-83 wt % yield of liquid products at 380A degrees D<inverted exclamation>, 4.0 MPa, and feed space velocity of 1 h(-1). The catalyst acidity increases with increasing tungsten oxide content, leading to an increase in the content of decarboxylation/decarbonylation products and isoparaffins in the product mixture.

引用

页码：1944 / 1952

页数：9

共 50 条

[1] Hydrodeoxygenation of Vegetable Oil on NiMoS/WO3–Al2O3 Catalysts
A. A. Nepomnyashchiy
E. A. Buluchevskiy
A. V. Lavrenov
V. L. Yurpalov
T. I. Gulyaeva
N. N. Leont’eva
V. P. Talzi
[J]. Russian Journal of Applied Chemistry, 2017, 90 : 1944 - 1952
[2] Hydrodeoxygenation of Vegetable Oil on NiMoS/WO3–Al2O3 Catalysts
Nepomnyashchiy, A.A.
Buluchevskiy, E.A.
Lavrenov, A.V.
Yurpalov, V.L.
Gulyaeva, T.I.
Leont’eva, N.N.
Talzi, V.P.
[J]. Russian Journal of Applied Chemistry, 2017, 90 (12): : 1944 - 1952
[3] EPR Spectroscopic and Thermal Analysis Study of Spent NiMo/WO3-Al2O3 Catalysts for Hydrodeoxygenation of Vegetable Oil
Yurpalov, V. L.
Drozdov, V. A.
Antonicheva, N., V
Nepomnyashchiy, A. A.
Buluchevskiy, E. A.
Lavrenov, A., V
[J]. KINETICS AND CATALYSIS, 2019, 60 (02) : 231 - 236
[4] Sunflower Oil Hydrodeoxygenation in the Presence of NiMoS/B2O3-Al2O3 Catalysts
Nepomnyashchii, A. A.
Buluchevskii, E. A.
Lavrenov, A., V
[J]. PETROLEUM CHEMISTRY, 2019, 59 (09) : 1049 - 1054
[5] Hydrodeoxygenation of Sunflower Oil over NiMoS/MoO3-Al2O3 and NiMoS/P2O5-Al2O3 Catalysts
Nepomnyashchiy, A. A.
Buluchevskiy, E. A.
Karpova, T. R.
Lavrenov, A., V
[J]. 21ST CENTURY: CHEMISTRY TO LIFE, 2019, 2143
[6] Sunflower Oil Hydrodeoxygenation in the Presence of NiMoS/B2O3–Al2O3 Catalysts
A. A. Nepomnyashchii
E. A. Buluchevskii
A. V. Lavrenov
[J]. Petroleum Chemistry, 2019, 59 : 1049 - 1054
[7] EPR Spectroscopic and Thermal Analysis Study of Spent NiMo/WO3–Al2O3 Catalysts for Hydrodeoxygenation of Vegetable Oil
V. L. Yurpalov
V. A. Drozdov
N. V. Antonicheva
A. A. Nepomnyashchiy
E. A. Buluchevskiy
A. V. Lavrenov
[J]. Kinetics and Catalysis, 2019, 60 : 231 - 236
[8] FORMATION OF TUNGSTEN SITES IN THE WO3-AL2O3 SYSTEM
MELKUMYAN, FS
MOLODOZHENYUK, TB
VOROBEV, VN
RAZIKOV, KK
[J]. JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1988, 61 (10): : 2000 - 2005
[9] Hydrodeoxygenation of cracked vegetable oil using CoMo/Al2O3 and Pt/C catalysts
Baldauf E.
Sievers A.
Willner T.
[J]. International Journal of Energy and Environmental Engineering, 2016, 7 (3) : 273 - 287
[10] The direct hydrodeoxygenation of vegetable oil over Pt-Sn/Al2O3 catalysts
Chistyakov, Andrey V.
Tsodikov, Mark V.
Zharova, Polina A.
Kriventsov, Vladimir V.
Corbetta, Michele
Manenti, Flavio
[J]. Chemical Engineering Transactions, 2017, 57 : 871 - 876

← 1 2 3 4 5 →