Dithieno[3,2-b:2′,3′-d]pyrrole-based materials: Synthesis and application to organic electronics

被引:107
|
作者
Rasmussen, Seth C. [1 ]
Evenson, Sean J. [1 ]
机构
[1] N Dakota State Univ, Dept Chem & Biochem, NDSU Dept 2735, Fargo, ND 58108 USA
基金
美国国家科学基金会;
关键词
Conjugated polymers; Dithieno[3,2-b:2 ',3 '-d]pyrroles; Reduced band gap; Low band gap; Field-effect transistors; Organic photovoltaics; BAND-GAP POLYMERS; CONJUGATED POLYMERS; HIGHLY FLUORESCENT; PHOTOVOLTAIC PROPERTIES; FUNCTIONALIZED POLYTHIOPHENES; ELECTROCHEMICAL PREPARATION; BUILDING-BLOCKS; N-ALKYL; DONOR; ACCEPTOR;
D O I
10.1016/j.progpolymsci.2013.04.004
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The application of dithieno[3,2-b:2',3'-d]pyrroles (DTPs) in conjugated organic polymers has resulted in a variety of materials with reduced and low band gaps that exhibit high carrier mobilities, as well as enhanced solution and solid-state fluorescence. While DTP-based materials date back to the early 1990s, significant advances in the preparation and scope of these materials have been reported over the past decade. In this current report, we provide the first full review of DTP-based materials, highlighting in particular the recent advances made in the synthesis of both monomeric DTPs and their resulting materials, as well as the current progress of their application to various devices, including FETs, OPVs, OLEDs, and electrochromics. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1773 / 1804
页数:32
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