Analytical and numerical study of detector sensitivity and resolution effects on metastable zone width

被引:6
|
作者
Kubota, Noriaki [1 ]
Kobari, Masanori [2 ,3 ]
Hirasawa, Izumi [3 ]
机构
[1] Iwate Univ, Dept Chem & Bioengn, Morioka, Iwate 020, Japan
[2] JGC Corp, EN Technol Ctr, Nishi Ku, Yokohama, Kanagawa, Japan
[3] Waseda Univ, Sch Sci & Engn, Dept Appl Chem, Shinjuku Ku, Tokyo, Japan
来源
CRYSTENGCOMM | 2013年 / 15卷 / 11期
关键词
INDUCTION TIME; PARACETAMOL; PARAMETERS;
D O I
10.1039/c2ce26968f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The effects of the sensitivity and resolution of a detector on metastable zone width (MSZW) were theoretically studied by using analytical and numerical methods. The detector sensitivity and the detector resolution were defined here as the minimum detectable number density of crystals (N/M)(det) and the minimum detectable size of crystals, respectively. Both the sensitivity and resolution had significant effects on MSZW. The MSZW became larger as the sensitivity was decreased (i.e., the value of (N/M)(det) was increased). It also became larger with a decrease in the resolution (i.e., an increase in the minimum detectable size). The effect of the resolution was less significant than that of the sensitivity. The effect of nucleus size on MSZW is also discussed. The MSZW reading in an actual experiment, where the minimum detectable size is expected to be much larger than the nucleus size, was suggested not to depend on nucleus size.
引用
收藏
页码:2091 / 2098
页数:8
相关论文
共 50 条
  • [1] Study on the metastable zone width of ketoprofen
    Lu, YH
    Ching, CB
    CHIRALITY, 2006, 18 (04) : 239 - 244
  • [2] Effects of impurity ions on solubility and metastable zone width of phosphoric acid
    Ma, Yong
    Zhu, Jiawen
    Ren, Hongrui
    Chen, Kui
    CRYSTAL RESEARCH AND TECHNOLOGY, 2009, 44 (12) : 1313 - 1318
  • [3] Effects of Impurity Ions on the Metastable Zone Width of Phosphoric Acid in Tributyl Phosphate
    Ma, Yong
    Wang, Zhou
    Zhou, Jianying
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (09): : 2909 - 2913
  • [4] Effects of Different Organic Acids on Solubility and Metastable Zone Width of Zinc Lactate
    Zhang, Xiangyang
    Qian, Gang
    Zhou, Xinggui
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (11): : 2963 - 2970
  • [5] Determination of solubility and metastable zone width of rebaudioside A and study on its crystallization process
    Guo S.
    Wu S.
    Su X.
    Gao W.
    Niu Z.
    Gong J.
    Huagong Xuebao/CIESC Journal, 2021, 72 (08): : 3997 - 4008
  • [6] Effects of detector sensitivity and resolution on induction time reading
    Kubota, Noriaki
    Kobari, Masanori
    Hirasawa, Izumi
    CRYSTENGCOMM, 2014, 16 (06): : 1103 - 1112
  • [7] Effects of Cooling Rate, Saturation Temperature, and Solvent on the Metastable Zone Width of Triethanolamine Hydrochloride
    Zhang, Yan
    Li, Zhibao
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (10) : 6375 - 6381
  • [8] Effects of agitation rates over metastable zone width (MSZW) of concentration for cane sugar crystallization
    Sanchez-Sanchez, K. B.
    Bolanos-Reynoso, E.
    Mendez-Contreras, J. M.
    Cerecero-Enriquez, R.
    REVISTA MEXICANA DE INGENIERIA QUIMICA, 2020, 19 (02): : 731 - 744
  • [9] Effects of different temperatures and additives on the metastable zone width precipitation kinetics of NaBO2
    Mustafa Kaya
    Ayhan Abdullah Ceyhan
    Ömer Şahin
    Russian Journal of Physical Chemistry A, 2014, 88 : 402 - 408
  • [10] Effects of different temperatures and additives on the metastable zone width precipitation kinetics of NaBO2
    Kaya, Mustafa
    Ceyhan, Ayhan Abdullah
    Sahin, Omer
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (03) : 402 - 408