Catalytic Combustion Type Carbon Monoxide Sensor Based on CuO-Co3O4 Catalyst

被引:1
|
作者
Huang Cai-Xia [1 ]
Gao Guo-Qiang [1 ]
机构
[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China
关键词
sensors; air pollution and industrial hygiene; copper; cobalt; CuO-Co3O4; negative temperature coefficient thermistor; catalytic combustion; CO OXIDATION; OXIDE; CELL;
D O I
10.3969/j.issn.1001-4861.2013.00.157
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Composite material CuO-Co3O4 was prepared by a co-precipitation method. A catalytic combustion CO sensor was fabricated by using CuO-Co3O4 as the sensing material and NTCT (Negative Temperature Coefficient Thermistor) as the heating resistance. The limit of quantification for the sensor is 0.034 9 mg.L-1. The phase composition and surface morphology of the composite material were characterized by X-ray diffraction (XRD) and field emission scanning electron microscope (FESEM). When the calcination temperature of CuO-Co3O4 is 400 degrees C, the sensor's sensitivity to CO reaches maximum. The sensor shows good linear relationship between response signals and CO concentration from 0.034 9 to 0.582 mg.L-1 at the operating voltage of 9 V and the linear correlation coefficient is 0.979. The 90% response and recovery time to 0.582 mg.L-1 CO is 24 s and 68 s, respectively.
引用
收藏
页码:1135 / 1140
页数:6
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