Two shear flow regimes in nematic liquid crystals: Near a charged surface and in the bulk

被引:9
|
作者
Zakharov, AV [1 ]
Dong, RY
机构
[1] Russian Acad Sci, St Petersburg Inst Machine Sci, St Petersburg 199178, Russia
[2] Brandon Univ, Dept Phys & Astron, Brandon, MB R7A 6A9, Canada
来源
JOURNAL OF CHEMICAL PHYSICS | 2002年 / 116卷 / 14期
关键词
D O I
10.1063/1.1460864
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Laminar and tumbling flow regimes in a high shear flow, as well as transition from a flow alignment regime to a tumbling situation are investigated in the polar liquid crystal p-n-hexyloxybenzylidenep(')-aminobenzonitrile (HBAB) near a charged surface. The relaxation of the alignment angle theta(tau) to its equilibrium theta(bulk) is calculated using the conventional Erickson-Leslie theory for the case of homeotropic alignment of HBAB at a charged indium tin oxide-coated glass plate and for the temperature range in which HBAB exhibits a nematic phase. In accordance with earlier Couette flow experiments, our calculations of the relaxation process for temperatures below 365 K show that the alignment angle is characterized by relaxing to a theta(bulk) of zero value, indicating that the steady laminar flow may break up into a tumbling flow. The nature of the hydrodynamic instability under high shear flow rates is also discussed for HBAB. (C) 2002 American Institute of Physics.
引用
收藏
页码:6348 / 6353
页数:6
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