Preparation and reactions of heteroaryl organomagnesium compounds

被引:39
|
作者
Ila, H
Baron, O
Wagner, AJ
Knochel, P
机构
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
[2] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
关键词
D O I
10.1246/cl.2006.2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The halogen/magnesium-exchange reaction has opened new perspectives in organic synthesis and has considerably extended the range of available functionalized aryl and heteroaryl magnesium compounds bearing functional groups such as ester, nitrile, iodide, imine, or even sensitive groups like nitro, hydroxy, and boronic esters. The present review Summarizes the applications of these functionalized heteroaryl- and arylmagnesium compounds for the synthesis of a wide variety of regiospecifically functionalized five- and six-membered heterocycles.
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页码:2 / 7
页数:6
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