Synthesis, structure and oxidation studies of a dinuclear copper(I)-copper(II) complex:: [Cu2(bdpdz)2](ClO4)3

被引：18
|
作者：
Manzur, J
García, AM
Vega, A
Spodine, E
机构：
[1] Univ Chile, Fac Ciencias Fis & Matemat, Santiago, Chile
[2] Univ Chile, Fac Ciencias Quim & Farmaceut, Santiago, Chile
来源：
POLYHEDRON | 1999年 / 18卷 / 18期
关键词：
copper complexes; mixed valence; structure; oxidation; binucleating ligand;
D O I：
10.1016/S0277-5387(99)00136-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A dinuclear copper complex containing the ligand 3,6-bis(di-2-pyridyrmethyl) pyridazine, bdpdz, [Cu-2(bdpdz)(2)](ClO4)(3), was prepared and its structure determined by X-ray analysis. The compound consists of a dinuclear mixed valence copper(I)-copper(II) entity with localised valences, co-ordinated to two bridging ligand molecules. The geometry around the copper(I) centre is distorted tetrahedral, while that of the copper(II) centre is tetragonally distorted octahedral. Oxidation studies reveal that the compound does not exhibit phenolase activity. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2399 / 2404
页数：6
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