Plasticization of Cellulose Nitrate by 4-Nitrophtalic Acid Esters

被引：2
|
作者：
Golubev, A. E. [1 ]
Neshitova, A. N. [2 ]
Singin, P. V. [3 ]
Kuvshinova, S. A. [2 ]
Burmistrov, V. A. [2 ]
Koifman, O. I. [2 ,4 ]
机构：
[1] Res Inst Polymer Mat, Ul Chistopolskaya 16, Perm, Russia
[2] Ivanovo State Univ Chem & Technol, Ivanovo, Russia
[3] Ivanovo Res Inst Film Mat & Synthet Leather Tech, Ivanovo, Russia
[4] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 12期
关键词：
nitrocellulose; nitro-substituted plasticizers; dibutyl phthalate; rheology; dynamic viscosity; activation entropy of viscous flow; physical mechanical properties;
D O I：
10.1134/S107036321712057X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The rheological properties of nitrocellulose solutions in cyclohexanone in the presence of phthalic and 4-nitrophthalic diester plasticizers were studied by rotational viscometry to reveal a behavior similar to that of Newtonian fluids. The activation parameters of the viscous flow regime were calculated. An influence of nitroplasticizers and dibutyl phthalate on the rheology of nitrocellulose was established. The influence of plasticizers on the mechanical properties of nitrocellulose films was discussed.
引用
收藏
页码：3086 / 3092
页数：7
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