In situ synthesis of a silicon flake/nitrogen-doped graphene-like carbon composite from organoclay for high-performance lithium-ion battery anodes

被引:46
|
作者
Chen, Qingze [1 ,2 ]
Zhu, Runliang [1 ]
He, Qiuzhi [1 ,2 ]
Liu, Shaohong [3 ,4 ]
Wu, Dingcai [3 ,4 ]
Fu, Haoyang [1 ,2 ]
Du, Jing [1 ,2 ]
Zhu, Jianxi [1 ]
He, Hongping [1 ,2 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Geochem, CAS Key Lab Mineral & Metallogeny, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Guangdong, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Sun Yat Sen Univ, Mat Sci Inst, PCFM Lab, Guangzhou 510275, Guangdong, Peoples R China
[4] Sun Yat Sen Univ, GDHPRC Lab, Sch Chem, Guangzhou 510275, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
CAPACITY ANODE; NANOPARTICLES; MICROSPHERES; CHALLENGES; STORAGE;
D O I
10.1039/c8cc10036e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A silicon flake/nitrogen-doped graphene-like carbon composite was prepared from organoclay via an in situ strategy, involving carbonization followed by low-temperature aluminothermic reduction. The preformed carbon sheets within the confined interlayer space of clay acted as nanotemplates for in situ synthesizing silicon flakes. As a lithium-ion battery anode, the composite exhibited excellent electrochemical properties.
引用
收藏
页码:2644 / 2647
页数:4
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