Liquid crystalline microspheres of azobenzene amphiphiles formed by thermally induced pH changes in binary water- hydrolytic ionic liquid media

被引：2
|
作者：
Kang, Tejwant Singh [1 ,2 ]
Morikawa, Masa-aki [1 ,3 ]
Kimizuka, Nobuo [1 ,3 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Nishi Ku, 744 Motooka, Fukuoka, Fukuoka 8190395, Japan
[2] Guru Nanak Dev Univ, Dept Chem, Amritsar 143005, Punjab, India
[3] Kyushu Univ, CMS, Nishi Ku, 744 Motooka, Fukuoka, Fukuoka 8190395, Japan
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 38期
关键词：
BILAYER-MEMBRANES; SELF-ORGANIZATION; VESICLES; BEHAVIOR;
D O I：
10.1039/c9cc01731c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Anionic azobenzene-containing bilayered membranes dispersed in binary water-ionic liquid (IL) media undergo proton-responsive transformation into liquid crystalline microspheres (LCMs). This transformation was induced by protons released by the heat-induced hydrolysis of tetrafluoroborate ions in the ILs. This work demonstrates the first beneficial use of hydrolysis-susceptible ILs in chemistry.
引用
收藏
页码：5459 / 5462
页数：4
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