Chemicals from ethanol-The acetone one-pot synthesis

被引：52

作者：

Rodrigues, Clarissa P. ^{[1
]}

Zonetti, Priscila C. ^{[1
]}

Silva, Camila G. ^{[1
]}

Gaspar, Alexandre B. ^{[1
]}

Appel, Lucia G. ^{[1
]}

机构：

[1] Inst Nacl Tecnol, Div Catalise & Proc Quim, BR-21081312 Rio De Janeiro, RJ, Brazil

来源：

APPLIED CATALYSIS A-GENERAL | 2013年 / 458卷

关键词：

Acetone; Ethanol; Zirconia; Ketonization; IN-SITU DRIFT; ACETALDEHYDE ADSORPTION; OXIDE CATALYST; ACETIC-ACID; CONVERSION; ZIRCONIA; METHANOL; KETONIZATION; CHEMISTRY;

D O I：

10.1016/j.apcata.2013.03.028

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ethanol is a platform molecule that can generate many different products employing one-pot processes and multifunctional catalysts. The synthesis of acetone from ethanol is a good example of these processes. Some authors studied the generation of acetone from ethanol and proposed mechanisms which are not fully in agreement. This work using catalyst physical mixtures and IR spectroscopy (DRIFTS) is consistent with the generation of acetone from ethanol by ketonization of carboxylates which are obtained by dehydrogenation of this alcohol followed by oxidation. These results confirm that physical mixtures of catalysts can be a valuable tool in order to study the mechanism of multi-step reactions. (c) 2013 Elsevier B.V. All rights reserved.

引用

页码：111 / 118

页数：8

共 50 条

[1] Chemicals from ethanol-The ethyl acetate one-pot synthesis
Gaspar, A. B.
Esteves, A. M. L.
Mendes, F. M. T.
Barbosa, F. G.
Appel, L. G.
APPLIED CATALYSIS A-GENERAL, 2009, 363 (1-2) : 109 - 114
[2] Chemicals from ethanol - The dehydrogenative route of the ethyl acetate one-pot synthesis
Zonetti, Priscila C.
Celnik, Johnatan
Letichevsky, Sonia
Gaspar, Alexandre B.
Appel, Lucia G.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 334 (1-2) : 29 - 34
[3] Heterogeneous Catalysts for the One-Pot Synthesis of Chemicals and Fine Chemicals
Climent, Maria J.
Corma, Avelino
Iborra, Sara
CHEMICAL REVIEWS, 2011, 111 (02) : 1072 - 1133
[4] Cyanide-Free One-Pot Synthesis of Methacrylic Esters from Acetone
Koyama, Minoru
Kawakami, Takafumi
Okazoe, Takashi
Nozaki, Kyoko
CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (46) : 10913 - 10917
[5] Bifunctionalized Hollow Nanospheres for the One-Pot Synthesis of Methyl Isobutyl Ketone from Acetone
Wang, Peng
Bai, Shiyang
Zhao, Jiao
Su, Panpan
Yang, Qihua
Li, Can
CHEMSUSCHEM, 2012, 5 (12) : 2390 - 2396
[6] One-Pot Biosynthesis of Acetone from Waste Poly(hydroxybutyrate)
Armijo-Galdames, Benjamin O.
Sadler, Joanna C.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2024, 12 (20): : 7748 - 7756
[7] One-pot synthesis of aryloxypropanediols from glycerol: towards valuable chemicals from renewable sources
Truscello, Ada M.
Gambarotti, Cristian
Lauria, Mirvana
Auricchio, Sergio
Leonardi, Gabriella
Shisodia, Suresh U.
Citterio, Attilio
GREEN CHEMISTRY, 2013, 15 (03) : 625 - 628
[8] One-pot synthesis
Anon
Chemical and Engineering News, 2002, 80 (46):
[9] One-pot synthesis
Chem Eng News, 5 (29):
[10] Pot economy and one-pot synthesis
Hayashi, Yujiro
CHEMICAL SCIENCE, 2016, 7 (02) : 866 - 880

← 1 2 3 4 5 →