Hole transport layer based on conjugated polyelectrolytes for polymer solar cells

被引：19
|
作者：
Moon, Sanghun [1 ]
Khadtare, Shubhangi [1 ]
Wong, Matthew [2 ]
Han, Sung-Hwan [1 ]
Bazan, Guillermo C. [2 ]
Choi, Hyosung [1 ]
机构：
[1] Hanyang Univ, Res Inst Nat Sci, Dept Chem, Seoul 133791, South Korea
[2] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2018年 / 518卷
基金：
新加坡国家研究基金会;
关键词：
Conjugated polyelectrolytes; Hole transport layer; Polymer solar cells; Bulk heterojunction; ORGANIC ELECTRONIC DEVICES; EFFICIENCY; PERFORMANCE; PEDOTPSS; PERMITTIVITY; INTERLAYERS;
D O I：
10.1016/j.jcis.2018.02.009
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We demonstrate the conjugated polyelectrolytes (CPEs) as efficient hole transport layer (HTL) of polymer solar cells. Replacing poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) with a CPEs with narrow bandgap results in both improvements in device efficiency and stability. In spite of their narrow bandgap, thin CPE films (thickness of similar to 30 nm) enable sufficient light absorption within the active layer. Enhancement of device efficiency is attributed to low surface roughness, high transmittance in visible region, and reduced charge transfer resistance. Compared to the device with PEDOT:PSS, pH neutral nature of CPEs may enhance device stability under ambient condition. (C) 2018 Elsevier Inc. All rights reserved.
引用
收藏
页码：21 / 26
页数：6
相关论文
共 50 条
  • [1] In situ Polymerization of PEDOT: π-Conjugated Polyelectrolyte and Application as Hole Transport Layer in Polymer Solar Cells
    Xiao, Yu-juan
    He, Qian-nan
    Zhou, Huan-yu
    Xu, Hai-tao
    Tan, Li-cheng
    Chen, Yi-wang
    [J]. ACTA POLYMERICA SINICA, 2018, (02): : 257 - 265
  • [2] Polymer solar cells employing conjugated polyelectrolytes with different countercations
    Shi, Yueqin
    Yang, Enxiang
    Zhang, Jun
    Ji, Zhenguo
    [J]. COLLOID AND POLYMER SCIENCE, 2019, 297 (10) : 1313 - 1319
  • [3] Conjugated polyelectrolytes as promising hole transport materials for inverted perovskite solar cells: effect of ionic groups
    Liu, Pang-Hsiao
    Chuang, Ching-Hsiang
    Zhou, Yi-Ling
    Wang, Shih-Hao
    Jeng, Ru-Jong
    Rwei, Syang-Peng
    Liau, Wen-Bin
    Wang, Leeyih
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (47) : 25173 - 25177
  • [4] Polymer solar cells employing conjugated polyelectrolytes with different countercations
    Yueqin Shi
    Enxiang Yang
    Jun Zhang
    Zhenguo Ji
    [J]. Colloid and Polymer Science, 2019, 297 : 1313 - 1319
  • [5] Triphenylamine-Based Conjugated Polyelectrolyte as a Hole Transport Layer for Efficient and Scalable Perovskite Solar Cells
    Harit, Amit Kumar
    Jung, Eui Dae
    Ha, Jung Min
    Park, Jong Hyun
    Tripathi, Ayushi
    Noh, Young Wook
    Song, Myoung Hoon
    Woo, Han Young
    [J]. SMALL, 2022, 18 (05)
  • [6] Enhancing Efficiency and Stability of Polymer Solar Cells Based on CuI Nanoparticles as the Hole Transport Layer
    Zhong, Yuancong
    Li, Yi
    Lan, Xuyan
    Wang, Jue
    Wang, Jianing
    Zhang, Yong
    [J]. IEEE JOURNAL OF PHOTOVOLTAICS, 2021, 11 (03): : 668 - 673
  • [7] Enhancing performance and stability of perovskite solar cells using hole transport layer of small molecule and conjugated polymer blend
    Hwang, Hansu
    Park, Sungmin
    Heo, Jin Hyuck
    Kim, Wansun
    Ahn, Hyungju
    Kim, Taek-Soo
    Im, Sang Hyuk
    Son, Hae Jung
    [J]. JOURNAL OF POWER SOURCES, 2019, 418 : 167 - 175
  • [8] Conjugated polyelectrolyte hole transport layer for inverted-type perovskite solar cells
    Choi, Hyosung
    Mai, Cheng-Kang
    Kim, Hak-Beom
    Jeong, Jaeki
    Song, Seyeong
    Bazan, Guillermo C.
    Kim, Jin Young
    Heeger, Alan J.
    [J]. NATURE COMMUNICATIONS, 2015, 6
  • [9] Conjugated polyelectrolyte hole transport layer for inverted-type perovskite solar cells
    Hyosung Choi
    Cheng-Kang Mai
    Hak-Beom Kim
    Jaeki Jeong
    Seyeong Song
    Guillermo C. Bazan
    Jin Young Kim
    Alan J. Heeger
    [J]. Nature Communications, 6
  • [10] The effect of hole transport layer on the thermal stability of inverted polymer solar cells
    Lin, Ming-Chih
    Huang, Yu-Ching
    Yen, Chia-Te
    Tsao, Cheng-Si
    Lin, Ming-Chih
    [J]. POLYMER DEGRADATION AND STABILITY, 2016, 134 : 245 - 250
12345