Isomerization of n-hexane over platinum loaded zeolites

被引:8
|
作者
Lee, JK
Lee, HT
Rhee, HK
机构
[1] Department of Chemical Engineering, Seoul National University, Kwanak-ku
来源
关键词
n-hexane; isomerization; Pt/H-beta; Pt/H-MOR;
D O I
10.1007/BF02064746
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of the calcination temperature of bifunctional Pt/zeolites on the isomerization of n-hexane has been investigated. The catalyst calcined at 350 degrees C showed the highest metal dispersity and the best activity. The higher selectivity of dimethylbutanes over Pt/H-beta than over Pt/H-MOR might be attributed to the combined effect of acidity, channel structure and pore size of zeolites.
引用
收藏
页码:323 / 337
页数:15
相关论文
共 50 条
  • [1] Isomerization of n-hexane over Platinum loaded zeolite catalysts
    Yashima, T
    Wang, ZB
    Kamo, A
    Yoneda, T
    Komatsu, T
    [J]. CATALYSIS TODAY, 1996, 29 (1-4) : 279 - 283
  • [2] Kinetics of hydro-isomerization of n-hexane over platinum containing zeolites
    vandeRunstraat, A
    Kamp, JA
    Stobbelaar, PJ
    vanGrondelle, J
    Krijnen, S
    vanSanten, RA
    [J]. JOURNAL OF CATALYSIS, 1997, 171 (01) : 77 - 84
  • [3] Skeletal isomerization of n-hexane over platinum-loaded h-mordenite
    Hollo, A
    Hancsok, J
    [J]. HUNGARIAN JOURNAL OF INDUSTRIAL CHEMISTRY, 1997, 25 (02): : 153 - 155
  • [4] Isomerization of n-hexane over sulfated zirconia:: Influence of hydrogen and platinum
    Duchet, JC
    Guillaume, D
    Monnier, A
    Dujardin, C
    Gilson, JP
    van Gestel, J
    Szabo, G
    Nascimento, P
    [J]. JOURNAL OF CATALYSIS, 2001, 198 (02) : 328 - 337
  • [5] Isomerization of n-pentane and n-hexane on modified zeolites
    Vasina, TV
    Masloboishchikova, OV
    Khelkovskaya-Sergeeva, EG
    Kustov, LM
    Houzvicka, J
    Zeuthen, P
    [J]. RUSSIAN CHEMICAL BULLETIN, 2000, 49 (11) : 1838 - 1841
  • [6] Isomerization of n-hexane over platinum ion-exchanged zeolite Beta
    Phatanasri, S
    Praserthdam, P
    Kularbkeaw, S
    Panichsarn, S
    [J]. REACTION KINETICS AND CATALYSIS LETTERS, 2000, 71 (02): : 281 - 287
  • [7] Isomerization of n-Hexane Over Platinum Ion-Exchanged Zeolite Beta
    Suphot Phatanasri
    Piyasan Praserthdam
    Sipira Kularbkeaw
    Somchai Panichsarn
    [J]. Reaction Kinetics and Catalysis Letters, 2000, 71 : 281 - 287
  • [8] Isomerization of N-hexane over sulfated zirconia: Influence of hydrogen and platinum.
    Duchet, JC
    Guillaume, D
    Monnier, A
    van Gestel, J
    Szabo, G
    Nascimento, P
    Decker, S
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U225 - U225
  • [9] HYDROCRACKING OF N-HEXANE AND CYCLOHEXANE OVER ZEOLITES
    VOORHIES, A
    HATCHER, WJ
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1969, 8 (04): : 361 - &
  • [10] Framework composition and activity of platinum-containing high-silica zeolites in n-hexane isomerization
    A. L. Lapidus
    M. N. Mikhailov
    I. V. Mishin
    A. A. Dergachev
    V. Z. Mordkovich
    [J]. Kinetics and Catalysis, 2009, 50 : 247 - 254