Base-free hydrogen generation from methanol using a bi-catalytic system

被引：111
|
作者：
Monney, Angele
Barsch, Enrico
Sponholz, Peter
Junge, Henrik
Ludwig, Ralf
Beller, Matthias [1 ]
机构：
[1] Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 06期
关键词：
FORMIC-ACID; RUTHENIUM COMPLEXES; DEHYDROGENATION; ECONOMY; ACCEPTORLESS; LIGANDS; ETHANOL;
D O I：
10.1039/c3cc47306f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A bi-catalytic system, in which Ru-MACHO-BH and Ru(H)(2)(dppe)(2) interact in a synergistic manner, was developed for the base-free dehydrogenation of methanol. A total TON > 4200 was obtained with only trace amounts of CO contamination (<8 ppm) in the produced gas.
引用
收藏
页码：707 / 709
页数：3
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