Enantioselective Synthesis of Nonracemic Geminal Silylboronates by Pt-Catalyzed Hydrosilylation

被引：55
|
作者：
Szymaniak, Adam A. [1 ]
Zhang, Chenlong [1 ]
Coombs, John R. [1 ]
Morken, James P. [1 ]
机构：
[1] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA
来源：
ACS CATALYSIS | 2018年 / 8卷 / 04期
关键词：
hydrosilylation; silicon; boron; catalysis; asymmetric; ASYMMETRIC HYDROSILYLATION; COMPLEXES; BORON; DIBORYLMETHANE; HYDROSILATION; CONSTRUCTION; ADDITIONS; MECHANISM; OLEFINS; KETONES;
D O I：
10.1021/acscatal.8b00221
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral nonracemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.
引用
收藏
页码：2897 / +
页数：9
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