A Simple Chemical Vapor Deposition Method for the Production of Highly Conductive Polymer Poly(3,4-ethylenedioxythiophene)

被引：0
|
作者：
Reig-i-Plessis, Dalmau [1 ]
Panaitescu, Eugen [1 ]
Baskaran, Akshai [1 ]
Menon, Latika [1 ]
机构：
[1] Northeastern Univ, Dept Phys, Boston, MA 02199 USA
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2013年 / 13卷 / 06期
关键词：
PEDOT; Hole Transport Material; HOMO; Vapor-Phase Polymerized; DSSC; SOLAR-CELLS; FILMS; PEDOT;
D O I：
10.1166/jnn.2013.7432
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Conductive thin films of Poly(3,4-ethylenedioxythiophene) (PEDOT) have been successfully deposited on a variety of substrates by a simple chemical vapor deposition (CVD) method starting from the liquid monomer (EDOT) and using FeCl3 as a catalyst. Resistivity measurements indicated very good conductivity of the material, comparable with other previously reported values for PEDOT deposited by CVD. Further cyclic voltammetry measurements indicated a value of around -4.7 eV for the HOMO level of PEDOT in the deposited films, in agreement with other reported values. This value is within the bandgap of most semiconductors, and together with the relative low internal resistance makes our material an ideal candidate as a solid-state hole transport material for dye sensitized solar cells.
引用
收藏
页码：4045 / 4051
页数：7
相关论文
共 50 条
  • [1] Synthesis of highly conductive poly(3,4-ethylenedioxythiophene) fiber by simple chemical polymerization
    Baik, Woonphil
    Luan, Wanquiang
    Zhao, Ren He
    Koo, Sangho
    Kim, Kyu-Sik
    [J]. SYNTHETIC METALS, 2009, 159 (13) : 1244 - 1246
  • [2] Chemical sensors based on highly conductive poly(3,4-ethylenedioxythiophene) nanorods
    Jang, J
    Chang, M
    Yoon, H
    [J]. ADVANCED MATERIALS, 2005, 17 (13) : 1616 - +
  • [3] Progress in Synthesis of Conductive Polymer Poly(3,4-Ethylenedioxythiophene)
    Nie, Shisong
    Li, Zaifang
    Yao, Yuyuan
    Jin, Yingzhi
    [J]. FRONTIERS IN CHEMISTRY, 2021, 9
  • [4] Towards a transparent, highly conductive poly(3,4-ethylenedioxythiophene)
    Ha, YH
    Nikolov, N
    Pollack, SK
    Mastrangelo, J
    Martin, BD
    Shashidhar, R
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (06) : 615 - 622
  • [5] Preparation of highly conductive gold-poly(3,4-ethylenedioxythiophene) nanocables and their conversion to poly(3,4-ethylenedioxythiophene) nanotubes
    Lu, Gewu
    Li, Chun
    Shen, Jiaoyan
    Chen, Zhaojia
    Shi, Gaoquan
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (16): : 5926 - 5931
  • [6] Oxidative chemical vapor deposition of electrically conducting poly(3,4-ethylenedioxythiophene) films
    Lock, John P.
    Im, Sung Gap
    Gleason, Karen K.
    [J]. MACROMOLECULES, 2006, 39 (16) : 5326 - 5329
  • [7] Oxidative atomized spray deposition of electrically conductive poly(3,4-ethylenedioxythiophene)
    Wood, Thomas J.
    Brown, Philip S.
    Badyal, Jas Pal S.
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (70) : 7741 - 7743
  • [8] Highly stretchable and conductive polymer material made from poly (3,4-ethylenedioxythiophene) and polyurethane elastomers
    Hansen, Thomas Steen
    West, Keld
    Hassager, Ole
    Larsen, Niels B.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (16) : 3069 - 3073
  • [9] Thermoelectric transport in conductive poly(3,4-ethylenedioxythiophene)
    Li, Meng
    Bai, Zuzhi
    Chen, Xiao
    Liu, Cong-Cong
    Xu, Jing-Kun
    Lan, Xiao-Qi
    Jiang, Feng-Xing
    [J]. CHINESE PHYSICS B, 2022, 31 (02)
  • [10] Thermoelectric transport in conductive poly(3,4-ethylenedioxythiophene)
    李萌
    柏祖志
    陈晓
    刘聪聪
    徐景坤
    蓝小琪
    蒋丰兴
    [J]. Chinese Physics B, 2022, 31 (02) : 14 - 26
12345